Source conductance scaling for high frequency superconducting quasiparticle receivers

It has been suggested that the optimum source conductance G(sub s) for the superconductor-insulator-superconductor (SIS) quasiparticle mixer should have a l/f dependence. This would imply that the critical current density of SIS junctions used for mixing should increase as frequency squared, a stringent constraint on the design of submillimeter SIS mixers, rather than in simple proportion to frequency as previously believed. We have used Tucker's quantum theory of mixing for extensive numerical calculations to determine G(sub s) for an optimized SIS receiver. We find that G(sub s) is very roughly independent of frequency (except for the best junctions at low frequency), and discuss the implications of our results for the design of submillimeter SIS mixers

Molybdenum complexes derived from the oxydianiline [(2-NH₂C₆H₄)₂O] : synthesis, characterization and ε-caprolactone ROP capability

The reaction of Na₂MoO₄ with 2,2′-oxydianiline (2-aminophenylether), (2-NH₂C₆H₄)₂O, LH₄, in DME (DME = 1,2-dimethoxyethane) in the presence of Et₃N and Me₃SiCl afforded either the bis(imido) molybdenum(VI) complex {Mo(L)Cl₂(DME)} (1), where L = (2-NC₆H₄)₂O, or the molybdenum(V) salt [Mo(L′)Cl₄][Et₃NH] (2), where L′ = [(2-NH₂C₆H₄)(2-NC₆H₄)O], depending on the work-up method employed. The same diamine reacted with in situ [Mo(NtBu)₂Cl₂(DME)] afforded a tetra-nuclear complex [Mo₄Cl₃(NtBu)₃(OSiMe₃)(μ₄-O)(L)₂(L′)₂]·2MeCN (3·2MeCN). The crystal structures of 1, 2 and 3·2MeCN have been determined. The structure of the bis(imido) complex 1 contains two unique molecules paired up via weak π-stacking, whereas the structure of 2 contains a chelating amine/imido ligand, and is made up of discrete units of two cations and two anions which are interacting via H-bonding. The tetra-nuclear structure 3 contains four different types of distorted octahedral molybdenum centre, and a bent Me₃SiO group thought to originate from the precursor synthesis. Complexes 1–3 have been screened for their ability to ring open polymerize (ROP) ε-caprolactone. For 1 and 3 (not 2), conversion rates were good (>90%) at high temperatures (100 °C) over 6–24 h, and the polymerization proceeded in a living manner

Gas Dynamics of the Nickel-56 Decay Heating in Pair-Instability Supernovae

Very massive 140-260 Msun stars can die as highly-energetic pair-instability supernovae (PI SNe) with energies of up to 100 times those of core-collapse SNe that can completely destroy the star, leaving no compact remnant behind. These explosions can synthesize $0.1-30$ Msun of radioactive Ni56, which can cause them to rebrighten at later times when photons due to Ni56 decay diffuse out of the ejecta. However, heat from the decay of such large masses of Ni56 could also drive important dynamical effects deep in the ejecta that are capable of mixing elements and affecting the observational signatures of these events. We have now investigated the dynamical effect of Ni56 heating on PI SN ejecta with high-resolution two-dimensional hydrodynamic simulations performed with the CASTRO code. We find that expansion of the hot Ni56 bubble forms a shell at the base of the silicon layer of the ejecta about 200 days after the explosion but that no hydrodynamical instabilities develop that would mix Ni56 with the Si/O-rich ejecta. However, while the dynamical effects of Ni56 heating may be weak they could affect the observational signatures of some PI SNe by diverting decay energy into internal expansion of the ejecta at the expense of rebrightening at later times.Comment: Accepted to ApJ, 14 page

Assessing the critical material constraints on low carbon infrastructure transitions

We present an assessment method to analyze whether the disruption in supply of a group of materials endangers the transition to low-carbon infrastructure. We define criticality as the combination of the potential for supply disruption and the exposure of the system of interest to that disruption. Low-carbon energy depends on multiple technologies comprised of a multitude of materials of varying criticality. Our methodology allows us to assess the simultaneous potential for supply disruption of a range of materials. Generating a specific target level of low-carbon energy implies a dynamic roll-out of technology at a specific scale. Our approach is correspondingly dynamic, and monitors the change in criticality during the transition towards a low-carbon energy goal. It is thus not limited to the quantification of criticality of a particular material at a particular point in time. We apply our method to criticality in the proposed UK energy transition as a demonstration, with a focus on neodymium use in electric vehicles. Although we anticipate that the supply disruption of neodymium will decrease, our results show the criticality of low carbon energy generation increases, as a result of increasing exposure to neodymium-reliant technologies. We present a number of potential responses to reduce the criticality through a reduction in supply disruption potential of the exposure of the UK to that disruption

Mechanism for current saturation and energy dissipation in graphene transistors

From a combination of careful and detailed theoretical and experimental studies, we demonstrate that the Boltzmann theory including all scattering mechanisms gives an excellent account, with no adjustable parameters, of high electric field transport in single as well as double-oxide graphene transistors. We further show unambiguously that scattering from the substrate and superstrate surface optical (SO) phonons governs the high field transport and heat dissipation over a wide range of experimentally relevant parameters. Models that neglect SO phonons altogether or treat them in a simple phenomenological manner are inadequate. We outline possible strategies for achieving higher current and complete saturation in graphene devices.Comment: revtex, 5 pages, 3 figures, to appear in Phys. Rev. Lett

Scenarios of energy efficiency and CO2 emissions reduction potential in the buildings sector in China to year 2050

As China’s rapid urbanization continues and urban dwellers become more affluent, energy use in buildings is expected to grow. To understand how this growth can be slowed, we explore four scenarios for Chinese buildings, ranging from a high-energy-demand scenario with no new energy policies to lowest energy demand under a techno-economic-potential scenario that assumes full deployment of cost-effective efficient and renewable technologies by 2050. We show that, in the high energy demand scenario, building energy demand has an average annual growth rate of about 2.8%, with slower growth rates in the other three scenarios. In all scenarios, CO2 emissions grow slower than energy, with building CO2 peaking around 2045 in the high energy demand scenario, and as early as 2030 in the techno-economic-potential scenario. We show that although various technological solutions, systems and practices can be very effective in minimizing building energy use, rigorous policies are needed to overcome multiple implementation barriers